Buka umthombo wala UmCalahle ontuhlambili

[[File:Soda_bubbles_macro.jpg|thumb|Carbon dioxide]]

'''umCalahle ontuhlambili''' ( ifomula yevanga  '''CO2''') [[Umxube|ngumxube wevanga]] othalakala [[UHowo|njengohowo]] oluyisimunyane olungenambala olunesiluthi esingaba amaphesenti angama-53 ngaphezulu kunalawo womoya owomile. AmaChembe womCalahle ontuhlambili aqukethe [[iChwe]] lomCalahle oluthungelwe ngokuphindiwe emaChweni amabili [[IsOhwe|wesOhwe]]. UmCalahle ontuhlambili utholakala ngokwemvelo [[Umoyambulunga|kumoyambulunga]] kaNomkhubulwane njenge njengohowo oluncane. Imithombo yawo engokwemvelo ihlanganisa [[izintaba-mlilo]], ukusha kwamahlathi, iziphethu ezishisayo, ama-geyser, futhi uphuma [[nasematsheni asamCalahle]] ngokuncibilikiswa amanzi nayisimunyane. Ngenxa yokuthi umCalahle ontuhlambili uyancibilika [[Amanzi|emanzini]], utholakala ngokwemvelo emanzini angaphansi komhlaba, [[Umfula|imifula]] [[Ichibi|namachibi]], izingqimba zeqhwa, izinguzunga zeqhwa nasemanzini olwandle. Uyatholakala nasezingxenyeni [[Amafuthetshe|amafuthetshe]] nohowo lwemvelo. Umcalahle ontuhlambili unephunga elibukhali nelimunyu futhi ukhiqiza ukunambitheka kwamanzi ayiNaside emlonyeni. <ref>[https://www.healthline.com/nutrition/carbonated-water-good-or-bad Carbonated (Sparkling) Water: Good or Bad?] healthline.com</ref>Kodwa-ke, ekugxileni okuvamile awunaphunga.

== Umlando ==
[[File:Carbon-dioxide-crystal-3D-vdW.png|left|thumb| Isakhiwo somncwebe seqhwa elomile]]
umCalahle ontuhlambili kwakunguhowo lokuqala oluchazwa njengesiqa esihlukile. Cishe ngo-1640, <ref>{{Cite journal|title=The Pioneer in the Hygiene of Ventilation|last=DavidFraser Harris|date=September 1910|url=https://zenodo.org/record/2088803}}</ref> umthaki wemithi Jan Baptist van Helmont waphawula ukuthi lapho eshisa isalahle esitsheni esivaliwe, inqumbi  yomlotha yayiyiningi kunaleyo yesalahle yasekuqaleni. Isikhumusho sakhe sasiwukuthi   enye ingxenye yesalahle idluliselwe esiqeni esingabonakali ayesibiza ngokuthi "uhowo" noma "umoya wasendle" (i- ''spiritus sylvestris'' ). 

== Izakhi zevanga nezokubumbeka ==

=== uhlaka, ukubhonqeka nokuqhikizeka kwamachembe ===
 
Umlinganiso wamachembe omcalahle ontuhlambili uluqombotha futhi ulingenindeni yomlingazwe wawo wokulingana. Ubude besibhobqi somcalahle-sOhwe kumcalahle ontuhlambili ungu-116.3&nbsp;pm, mfushane ngokuphawulekayo kunobude obucishe bube ngu-140-pm besibhonqi esijwayelekile se-C-O, futhi sifushane kunamanye amaqembu amaningi asebenza ngokubhonqa ama-C-O njenge- carbonyls. Njengoba lilingenindeni, ichembe alinaso isikhashana se-dipole yamazuba.
[[File:Co2_vibrations.svg|left|thumb| imicikazo elulekayo nebhenayo yechembe le-CO <sub>2</sub> umCalahle ontuhlambili. Phezulu kwesobunxele: ukuzolula okulinganayo. Phezulu kwesokudla: ukwelulwa okungalingani. Umugqa ophansi: izindlela ezigoqekayo zokubhangqa.]]

=== Kwisixazululo samanzi ===
 
umCalahle ontuhlambili uyancibilika emanzini, lapho ubuyela emuva ubuye ubumbe H<nowiki></br></nowiki> H CO<nowiki></br></nowiki> H (isimunyane somcalahle), okuyisimunyane esibuthakathaka ngoba ukuhonyozeka kwaso emanzini kunga.

: CO2 + H2O ⇌ H2CO3

Ukuhlala kwe-hydration equilibrium kwe-carbonic acid kuyinto <math>K_{\mathrm h}=\frac{\rm{[H_2CO_3]}}{\rm{[CO_2(aq)]}}=1.70\times 10^{-3}</math> (ngo-25&nbsp;° C). Ngakho-ke, iningi lomcalahle ontuhlambili aliguqulwa libe yi-carbonic acid, kepha lihlala njengama- <sub>molecule e-CO 2</sub>, angathinti i-pH.

Ukugxila okuhlobene kwe- CO<nowiki></br></nowiki> CO, HCO CO CO kanye deprotonated amafomu HCO-<nowiki></br></nowiki> HCO ( bicarbonate ) ne- CO2−<nowiki></br></nowiki> CO ( carbonate ) incike kwi- pH.Njengoba kukhonjisiwe esakhiweni seBjerrum, emanzini angathathi hlangothi noma ane-alkaline encane (pH> 6.5), ifomu le-bicarbonate ligcwele (> 50%) liba kakhulu (> 95%) ku-pH yamanzi olwandle.Emanzini ane-alkaline kakhulu (pH> 10.4), ifomu elivelele (> 50%) yi-carbonate.Izilwandle, njengoba zine-alkaline emnene ene-pH ejwayelekile = 8.2-8.5, ziqukethe cishe i-120&nbsp;mg we-bicarbonate ngelitha ngalinye.

Ukuba yi- diprotic, i-carbonic acid inezakhi ezimbili zokuhlukaniswa kwe-asidi, eyokuqala yokuhlukaniswa kwe-bicarbonate (ebizwa nangokuthi i-hydrogen carbonate) ion (HCO <sub>3</sub> <sup>-</sup> ):

: H <sub>2</sub> CO <sub>3</sub> ⇌ HCO <sub>3</sub> <sup>-</sup> + H <sup>+</sup>
: ''K'' <sub>a1</sub> = 2.5× 10 −4 mol / L ; p ''K'' <sub>a1</sub> = 3.6 ku-25&nbsp;° C. 

Lokhu kungukuhlala ''kweqiniso'' kwe-acid dissociation okuchazwa njenge <math>K_{a1}=\frac{\rm{[HCO_3^-] [H^+]}}{\rm{[H_2CO_3]}}</math>, lapho i-denominator ifaka kuphela i-covalently binded H <sub>2</sub> CO <sub>3</sub> futhi ingafaki i-hydrated CO <sub>2</sub> (aq). Inani elincanyana kakhulu futhi elicashunwa njalo eliseduze no- 4.16× 10 −7 liyinani ''elibonakalayo'' elibalwe ekucabangeni (okungalungile) kokuthi yonke i-CO <sub>2</sub> encibilikile ikhona njenge-carbonic acid, ukuze <math>K_{\mathrm{a1}}{\rm{(apparent)}}=\frac{\rm{[HCO_3^-] [H^+]}}{\rm{[H_2CO_3] + [CO_2(aq)]}}</math> . Njengoba iningi le-CO <sub>2</sub> elichithakele lihlala njengamamolekyu e-CO <sub>2</sub>, i- ''K'' <sub>a1</sub> (ebonakalayo) inesilinganiso esikhulu kakhulu nenani elincane kakhulu kune- ''K'' <sub>a1</sub> yangempela. 

I- bicarbonate ion iyinhlobo ye- amphoteric engasebenza njenge-asidi noma njengesisekelo, kuya nge-pH yesisombululo.Ku- pH ephezulu, yehlukanisa kakhulu ne- carbonate ion (CO <sub>3</sub> <sup>2−</sup> ):

: I-HCO <sub>3</sub> <sup>-</sup> ⇌ CO <sub>3</sub> <sup>2−</sup> + H <sup>+</sup>
: ''K'' <sub>a2</sub> = 4.69× 10 -11 mol / L ; p ''K'' <sub>a2</sub> = 10.329

Ezidalweni ukukhiqizwa kwe-carbonic acid kukhishwa yi- enzyme, i- carbonic anhydrase.

=== Izakhiwo zomzimba ===
[[File:Dry_Ice_Pellets_Subliming.jpg|right|thumb| Amapellets "eqhwa elomile", ifomu elijwayelekile le-carbon dioxide eqinile]]
I-Carbon dioxide ayinambala. Ezingxenyeni eziphansi igesi ayinaphunga; noma kunjalo, ekugxileni okwanele ngokwanele, inephunga elibukhali, eline-esidi.Ekushiseni okujwayelekile nokucindezela, ubukhulu be-carbon dioxide buzungeze u-1.98&nbsp;kg / m <sup>3</sup>, cishe izikhathi eziyi-1.53 zomoya.

ICarbon dioxide ayinaso isimo 0.517engaphansi kuka-0.517 95 (10) I-MPa <ref>{{Cite journal|last1=Span|first1=Roland|last2=Wagner|first2=Wolfgang|date=1996-11-01|title=A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa|url=https://aip.scitation.org/doi/10.1063/1.555991|journal=Journal of Physical and Chemical Reference Data|volume=25|issue=6|page=1519|doi=10.1063/1.555991|bibcode=1996JPCRD..25.1509S|issn=0047-2689|access-date=2021-09-10|archivedate=2021-07-09|archiveurl=https://web.archive.org/web/20210709182537/https://aip.scitation.org/doi/10.1063/1.555991|deadurl=yes}}</ref> ( 5.11177 (99) i-atm ). 0.101 kwe-1 atm ( 0.101 MPa ), igesi ifaka ngqo esiqinile emazingeni okushisa angaphansi kuka- 194.6855(30) I-K <ref>{{Cite journal|last1=Span|first1=Roland|last2=Wagner|first2=Wolfgang|date=1996-11-01|title=A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple‐Point Temperature to 1100 K at Pressures up to 800 MPa|url=https://aip.scitation.org/doi/10.1063/1.555991|journal=Journal of Physical and Chemical Reference Data|volume=25|issue=6|page=1521|doi=10.1063/1.555991|bibcode=1996JPCRD..25.1509S|issn=0047-2689|access-date=2021-09-10|archivedate=2021-07-09|archiveurl=https://web.archive.org/web/20210709182537/https://aip.scitation.org/doi/10.1063/1.555991|deadurl=yes}}</ref> ( −78.4645(30) ° C ) kanye nezimbumbulu eziqinile ngqo kwigesi engaphezulu kwaleli zinga lokushisa. Esimeni sayo esiqinile, isikhutha ngokuvamile ibizwa ngokuthi yiqhwa elomile .
[[File:Carbon_dioxide_pressure-temperature_phase_diagram.svg|right|thumb| Ingcindezi yesigaba sokushisa se-carbon dioxide. Qaphela ukuthi yishadi le-log-lin.]]

== Izicelo ==
ICarbon dioxide isetshenziswa yimboni yokudla, imboni kawoyela, kanye nemboni yamakhemikhali. <ref name="kirk">{{Cite encyclopedia|first=Ronald|last=Pierantozzi|encyclopedia=Kirk-Othmer Encyclopedia of Chemical Technology|publisher=Wiley|year=2001|doi=10.1002/0471238961.0301180216090518.a01.pub2|isbn=978-0-471-23896-6}}</ref>Le nhlanganisela inokusetshenziswa okuhlukahlukene kokuhweba kepha okunye ukusetshenziswa kwayo okukhulu njengekhemikhali ukukhiqizwa kweziphuzo ezinekhabhoni; inikeza ukukhanya kweziphuzo ezine-carbonated ezifana namanzi we-soda, ubhiya newayini elikhazimulayo.

=== Isandulela samakhemikhali ===
Embonini yamakhemikhali, isikhutha sidliwa kakhulu njengesithako ekukhiqizeni i- urea, kusetshenziswa ingxenyana encane ukukhiqiza i- methanol nohla lweminye imikhiqizo.Ezinye izakhi ze-carboxylic acid ezifana ne- sodium salicylate zilungiswa kusetshenziswa i-CO <sub>2</sub> yi- Kolbe-Schmitt reaction.

Ngaphezu kwezinqubo ezijwayelekile ezisebenzisa i-CO <sub>2</sub> yokukhiqiza amakhemikhali, izindlela ze-electrochemical nazo ziyahlolwa ezingeni locwaningo.Ikakhulu, ukusetshenziswa kwamandla avuselelekayo ekukhiqizeni uphethiloli ovela ku-CO <sub>2</sub> (njenge-methanol) kuyaheha ngoba lokhu kungaholela ekubaseni okungathuthwa kalula futhi kusetshenziswe ngaphakathi kobuchwepheshe obuvamile bomlilo kepha kungabikho ukukhishwa kwe- <sub>CO 2.</sub> <ref>{{Cite journal|last1=Badwal|title=Emerging electrochemical energy conversion and storage technologies (open access)|pmc=4174133|pmid=25309898|doi=10.3389/fchem.2014.00079|page=79|volume=2|date=24 September 2014|journal=Frontiers in Chemistry|first5=Anthony F.|first1=Sukhvinder P. S.|last5=Hollenkamp|first4=Anand I.|last4=Bhatt|first3=Christopher|last3=Munnings|first2=Sarbjit S.|last2=Giddey|bibcode=2014FrCh....2...79B}}</ref>

Izitshalo zidinga i-carbon dioxide ukuqhuba i- photosynthesis.Umkhathi wezindawo zokugcina izithombo (uma ngabe usayizi omkhulu, kufanele) ucebiswe nge-CO <sub>2</sub> eyengeziwe ukugcina nokukhuphula izinga lokukhula kwezitshalo.Ngezinye lokuhlala eliphezulu kakhulu (izikhathi 100 lokuhlushwa asemkhathini, noma ngaphezulu), i-carbon dioxide angaba enobuthi ekuphileni isilwane, ngakho nokuvusa okuhlushwa ukuze 10,000 ppm (1%) noma ngaphezulu amahora ambalwa uyoqeda izinambuzane ezifana whiteflies futhi izibungu spider endaweni abamba ukushisa. <ref>{{Cite journal|last1=Stafford, Ned|title=Future crops: The other greenhouse effect|journal=Nature|volume=448|date=7 February 2007|doi=10.1038/448526a|issue=7153|bibcode=2007Natur.448..526S}}</ref>

=== Ekudleni ===
[[File:Soda_bubbles_macro.jpg|thumb|ICARBON DIOXIDE esiphuzweni]]

== Izinkomba ==
[[Category:Articles containing unverified chemical infoboxes]]
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[[Category:Short description matches Wikidata]]